Thermodynamic and transport properties of liquid and liquid mixtures have been used to understand the intermolecular interactions between the components of the mixture. The sound velocity, density and viscosity of binary liquid mixtures are important from practical and theoretical point of view to understand the liquid theory. In the present study sound velocity, density and viscosity have been measured of binary mixtures of 1, 3-dioxolane with pentanol, hexanol, heptanol, octanol, nonanol and decanol over the entire range of mole fraction at 298.15K, and atmospheric pressure. From these experimental measurements the excess molar volume (VmE), excess viscosity (ηE), acoustic impedance (ZE) and excess adiabatic compressibility (βadE), have been calculated. The excess molar volume (VmE), excess viscosity (ηE), acoustic impedance (ZE) and excess adiabatic compressibility (βadE), have been analyzed in terms of interactions arising due to structural effect, charge-transfer complexes and dipole-dipole interaction between unlike molecules. These deviations have been correlated by a polynomial Redlich-Kister equation. The excess properties are found to be eighter negative or positive depending on the molecular interactions and nature of the liquid mixtures. Excess properties provide important information in understanding the solute-solvent interaction in a solution. The excess molar volume (VmE), excess viscosity (ηE), acoustic impedance (ZE) and excess adiabatic compressibility (βadE), values have been interpreted to terms of the nature of intermolecular interactions between constituent molecules of mixtures.
| Published in | American Journal of Heterocyclic Chemistry (Volume 10, Issue 1) |
| DOI | 10.11648/j.ajhc.20241001.12 |
| Page(s) | 13-25 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2024. Published by Science Publishing Group |
1, 3-dioxolane, Mole Fraction, Excess Viscosity, Adiabatic Compressibility, Density, Sound Velocity, Molecular Interaction
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APA Style
Mishra, R. K., Sharma, D. K., Prajapati, C. P. (2024). Excess Molar Volume and Deviations in Viscosity of the Binary Liquid Mixtures Containing 1,3-Dioxolane + Alkanols at T = 298.15k. American Journal of Heterocyclic Chemistry, 10(1), 13-25. https://doi.org/10.11648/j.ajhc.20241001.12
ACS Style
Mishra, R. K.; Sharma, D. K.; Prajapati, C. P. Excess Molar Volume and Deviations in Viscosity of the Binary Liquid Mixtures Containing 1,3-Dioxolane + Alkanols at T = 298.15k. Am. J. Heterocycl. Chem. 2024, 10(1), 13-25. doi: 10.11648/j.ajhc.20241001.12
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Download@article{10.11648/j.ajhc.20241001.12,
author = {Ravi Kant Mishra and Dhirendra Kumar Sharma and Chandra Pal Prajapati},
title = {Excess Molar Volume and Deviations in Viscosity of the Binary Liquid Mixtures Containing 1,3-Dioxolane + Alkanols at T = 298.15k
},
journal = {American Journal of Heterocyclic Chemistry},
volume = {10},
number = {1},
pages = {13-25},
doi = {10.11648/j.ajhc.20241001.12},
url = {https://doi.org/10.11648/j.ajhc.20241001.12},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajhc.20241001.12},
abstract = {Thermodynamic and transport properties of liquid and liquid mixtures have been used to understand the intermolecular interactions between the components of the mixture. The sound velocity, density and viscosity of binary liquid mixtures are important from practical and theoretical point of view to understand the liquid theory. In the present study sound velocity, density and viscosity have been measured of binary mixtures of 1, 3-dioxolane with pentanol, hexanol, heptanol, octanol, nonanol and decanol over the entire range of mole fraction at 298.15K, and atmospheric pressure. From these experimental measurements the excess molar volume (VmE), excess viscosity (ηE), acoustic impedance (ZE) and excess adiabatic compressibility (βadE), have been calculated. The excess molar volume (VmE), excess viscosity (ηE), acoustic impedance (ZE) and excess adiabatic compressibility (βadE), have been analyzed in terms of interactions arising due to structural effect, charge-transfer complexes and dipole-dipole interaction between unlike molecules. These deviations have been correlated by a polynomial Redlich-Kister equation. The excess properties are found to be eighter negative or positive depending on the molecular interactions and nature of the liquid mixtures. Excess properties provide important information in understanding the solute-solvent interaction in a solution. The excess molar volume (VmE), excess viscosity (ηE), acoustic impedance (ZE) and excess adiabatic compressibility (βadE), values have been interpreted to terms of the nature of intermolecular interactions between constituent molecules of mixtures.
},
year = {2024}
}
TY - JOUR T1 - Excess Molar Volume and Deviations in Viscosity of the Binary Liquid Mixtures Containing 1,3-Dioxolane + Alkanols at T = 298.15k AU - Ravi Kant Mishra AU - Dhirendra Kumar Sharma AU - Chandra Pal Prajapati Y1 - 2024/09/29 PY - 2024 N1 - https://doi.org/10.11648/j.ajhc.20241001.12 DO - 10.11648/j.ajhc.20241001.12 T2 - American Journal of Heterocyclic Chemistry JF - American Journal of Heterocyclic Chemistry JO - American Journal of Heterocyclic Chemistry SP - 13 EP - 25 PB - Science Publishing Group SN - 2575-5722 UR - https://doi.org/10.11648/j.ajhc.20241001.12 AB - Thermodynamic and transport properties of liquid and liquid mixtures have been used to understand the intermolecular interactions between the components of the mixture. The sound velocity, density and viscosity of binary liquid mixtures are important from practical and theoretical point of view to understand the liquid theory. In the present study sound velocity, density and viscosity have been measured of binary mixtures of 1, 3-dioxolane with pentanol, hexanol, heptanol, octanol, nonanol and decanol over the entire range of mole fraction at 298.15K, and atmospheric pressure. From these experimental measurements the excess molar volume (VmE), excess viscosity (ηE), acoustic impedance (ZE) and excess adiabatic compressibility (βadE), have been calculated. The excess molar volume (VmE), excess viscosity (ηE), acoustic impedance (ZE) and excess adiabatic compressibility (βadE), have been analyzed in terms of interactions arising due to structural effect, charge-transfer complexes and dipole-dipole interaction between unlike molecules. These deviations have been correlated by a polynomial Redlich-Kister equation. The excess properties are found to be eighter negative or positive depending on the molecular interactions and nature of the liquid mixtures. Excess properties provide important information in understanding the solute-solvent interaction in a solution. The excess molar volume (VmE), excess viscosity (ηE), acoustic impedance (ZE) and excess adiabatic compressibility (βadE), values have been interpreted to terms of the nature of intermolecular interactions between constituent molecules of mixtures. VL - 10 IS - 1 ER -
Department of Chemistry, Institute of Basic Science, Bundelkhand University, Jhansi (U.P), India
Department of Chemistry, Institute of Basic Science, Bundelkhand University, Jhansi (U.P), India
Department of Chemistry, Institute of Basic Science, Bundelkhand University, Jhansi (U.P), India
